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233.


Problem 25.37 (RHK)


A quantity of ideal monatomic gas consists of n moles initially at temperature . The pressure and volume are then slowly doubled in such a manner as to trace out a straight line on pV diagram. In terms of n, R, and , we have to find (a) W, (b) , and (c) Q. (d) If one were to define an equivalent specific heat for the process, we have to calculate its value.


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As the change of pressure and volume is linear in the pV diagram and the pressure doubles when the volume doubles, the equation of the straight line relating the pressure-volume is

Also, the initial temperature of the gas is and the quantity of the gas is n moles, we have

(a)

The work done on the gas during the slow change described by the linear relation will be

(b)

The final temperature of the gas can be obtained from the equation of state.

The change in the internal energy of a monatomic ideal gas can be obtained from the initial and final temperatures.

(c)

The heat absorbed Q can be calculated from the first law of thermodynamics,

and

(d)

We define the equivalent specific heat